Comprehensive inorganic chemistry. volume 3: the halogens

CHEM3012 - Core Chemistry 3 Inorganic Reaction Mechanisms

The substitution of ligands in octahedral metal complexes is the most extensively mechanistically studied inorganic reaction. It is of fundamental importance, and a number of important observations and results are found. Substitution in octahedral systems was initially studied for classical coordination complexes in aqueous solutions. More recently some important observations have been made reg...

Halogens and the chemistry of the free troposphere

The role of halogens in both the marine boundary layer and the stratosphere has long been recognized, while their role in the free troposphere is often not considered in global chemical models. However, a careful examination of free-tropospheric chemistry constrained by observations using a full chemical data assimilation system shows that halogens do play a significant role in the free troposp...

Inorganic and Bio-inorganic Chemistry

Journal of Biological Inorganic Chemistry, 7 ( 3), 2002

The binding of carbon monoxide, a competitive inhibitor of many hydrogenases, to the active site of Desulfovibrio fructosovorans hydrogenase has been studied Journal of Biological Inorganic Chemistry, 7 ( 3), 2002 2 by infrared spectroscopy in a spectroelectrochemical cell. Direct evidence has been obtained of what redox states of the enzyme can bind extrinsic CO. Redox states A, B and SU do no...

Aids to Inorganic Chemistry